Cupellation is a very old and time consuming method to determine the silver fineness.
Cupellation is a refining process in metallurgy, where ores or alloyed metals are treated under very high temperatures and have controlled operations to separate noble metals, like gold and silver, from base metals like lead, copper, zinc, arsenic, antimony or bismuth, present in the ore.The process is based on the principle that precious metals do not oxidize or react chemically, unlike the base metals; so when they are heated at high temperatures, the precious metals remain apart and the others react forming slags or other compoundshttps://en.wikipedia.org/wiki/CupellationTouch needles, touchstone.
Georgius Agricola (1490–1555) described the use of the touchstone and touch needles for examining bullion, coins, and jewellery. Dutch silver town guilds assay rules and limitations 17th to 18th century.
The simplest method used for small work was the touch needle and touchstone, with little metal lost. The principle was simple; the touch needle, whose standard of fineness was precisely known, was scratched over a certain kind of black stone (lydite), such that a silver-colored stripe came on the stone. Than the various parts of the silver work to be tested were scratched over the stone, and the assayer's eye determined how the color of the lines diverged from the color of the first line made by the touch needle. More red in color than the touch needle line meant a higher admixture of copper and thus a lower silver fineness. An experienced assayer sees differences in silver content of 5 to 10 thousandths. The color determination was rather subjective and often triggered a quarrel among silversmiths, assayers and guild authorities. Nowadays the touch needle & stone is well-standardized and still the most widely used method.
Tremulierstrich/tremolierstich/zig zag line made by assayer taking a silver sample and to test if the silver sample was of the correct legal standard of fineness. The removed silver sample was compared to another fixed sample of silver with an accurate known legal standard of fineness.
Assaying by tremulierstrich or silver removal, again much depending on the knowledge and experience of the assayer, or the assayer's eye. With a tremble needle the assayer stabbed some silver out of the silver work for assaying. The removed silver sample together with a sample of silver of accurate known fineness was short and lightly annealed (heated) and then quickly cooled down. Comparison of the colors of the two samples, created by the heating, made the determination of the fineness possible. Assaying by tremulierstrich takes far more time compared to the use of touch needle and touchstone and was certainly not more accurate.
However the Guilds/ State/City/Mint authorities decided which assay method had to be applied. If both methods of testing either by touch needle or tremulierstrich were not conclusive or the assayer was in doubt and or the silversmith did not accept the outcome of the assay. The guild authorities ordered assay by Cupellation which could damage the silver work due to multiple silver removal.
During the Dutch silver guild period rules were strict but not all Dutch town guilds strictly obeyed the rules. During the time some guilds received a warning from State/Provincial Authorities for not following the assay rules and or sloppy assay work, even fraud.
Regards,
Peter