Postby quoti » Tue May 31, 2011 2:25 pm
Could you do a simple density test? You'd need a carefully graduated beaker marked in mL in which the jug would fit, and some water. You first weigh the item dry and in grams as accurately as possible. Fill the beaker with enough water that the item will be submerged when you place it in: note the water level. Place the item in the water so that it is completely submerged and note the new water level. The difference in water levels is the displacement in mL (math: final water level minus intial water level = displacement). You then divide the grams weight by the mL displacement, and if it is sterling, you should get a number very close to 10.2 - 10.3 on your calculator (meaning that 10.2 gm of sterling displaces 1 mL of water).
Silverplated items are often of nickel silver alloy (8.4-8.9 density), copper (8.9 density), zinc (7.1 density), or pewter/tin (7.3 or so), which as you can see would be easy to spot because of much lower density than sterling. The only base metals that would be higher than the 10.2-10.3 density of sterling that might be plated are rather unlikely metals: lead (11.3) and tungsten (19.3).
If you can get a really clearly marked beaker and a good gram scale (at least two decimal places), then this is the simplest way to see, and it will not hurt or damage the piece at all. If you have a university nearby, you might just take to the chemistry department and see if a student would like to determine the density for you (I've done that at my school before!). It is bizarre that's it not marked. Let us know what happens.